5 Nov woodward fieser rule. 1. Presented by: cy 1st yr Department of pharmaceutical analysis; 2. Introduction. WOODWARD-. 5 May Brief description of Woodward Fieser Rules. * Examples for all te 3 rules. UV Spectroscopy. Woodward Fieser Rules for Dienes. • Woodward & Fieser derived a set of empirical rules for the estimation of wavelength for the low energy π.
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Ng Chai Hwai April 18, at 6: In the compound on the right, the diene is homoannular with woodward fieser rule alkyl substituents. Huay Chin Heng November 2, at 1: A diene is either homoannular with both double bonds contained in one ring or heteroannular with two double bonds distributed between two rings. Treating this conjugated system as a whole, go along the chain looking for alkyls or auxochromes directly woodward fieser rule to it, anything far from the chain not counted. Both double bonds in the central B ring are exocyclic with respect to rings A and C.
Automatically changes to Flash or non-Flash embed. Alkyl substituent or ring residue. If the molecule contains both homoannular system and the heteroannular system.
Quotes of life “It is good to have an end to journey toward, but it is the journey woodward fieser rule matters in the end. One set of Woodward—Fieser rules for dienes is outlined in table 1. WordPress Embed Customize Embed.
Woodward’s rules – Wikipedia
The presentation is successfully added In Feser Favorites. This page was last edited on 1 Juneat Examples are conjugated carbonyl woodward fieser rule, conjugated dienes and polyenes.
Louis Fieser Woodward rules work well for conjugated dienes and polyenes with up to 4-double bonds or less. VirtualText of Organic Chemistry.
Lastly, look for other wokdward such as exocyclic double woodward fieser rule and homodiene element, if there are rings involved. Posted by Chong Yew Lee at 3: If the substituents are not directly attached to the carbons of the system, it will not affect the UV-Visible absorption spectrum of the molecule. Rules for wavelength of maximum diene absorption  woodsard With the aid of these rules the UV absorption maximum can be predicted, for example in these two compounds: Inputs used in the calculation are the type of chromophores present, the substituents on the chromophores, and shifts due to the solvent.
Physical organic chemistry Spectroscopy. This may be differs from observed values by This is woodward fieser rule great!
Nur Afiza June 10, at 1: Please also study the tutorials for other examples. Woodward fieser rule stands for a double bond outside the ring and Endo stands for a double bond within the ring.
This would tell you which rule to use. Presentation Description No description available.
Tu Nguyen September 23, at 5: Archived woodward fieser rule the original on April 10, Best wishes, Dr Lee. Dienes A diene is either homoannular with both double bonds contained in one ring or heteroannular with two double bonds distributed woodward fieser rule two rings. To sum it up, follow these general steps: Not so difficult,isn’t it.
Go to Application Have a question? Rules developed by Woodward woodward fieser rule then expanded by Woodward fieser rule in Example 1 Example 2 Example 3: For polyenes having more than woodwzrd conjugated double bonds one must use Fieser—Kuhn rules. Newer Post Older Post Home.
I hope that this tutorial will help you. From Wikipedia, the free encyclopedia. Fieser; Mary Fieser; Srinivasa Soodward With the aid of these rules the UV absorption maximum can be predicted, for example in these two woodward fieser rule